Question not clear.
Try and say it again in separate phrases and, if possible, a drawing.
But, rubbing my ball furiously, I think you are asking: can I measure AC without using a diode?
Assuming we are talking low voltage (e.g. on the secondary of a transformer) the answer is YES. Just use a resistor.
If the AC was, say less than 12V RMS, then a 10K resistor would be fine.
The resistor will limit the current and the clamping diodes will take care of the rest.
Do you know what clamping diodes are?
No point telling you these things if you haven't come across them. Check PIC Data Sheets where they show you the Port.pin I/O section.
From memory, there are a couple of PIC pins without clamps so check Data Sheet first.